研究者業績

川島隆幸

カワシマタカユキ (Takayuki Kawashima)

基本情報

所属: 学習院大学理学部客員教授
東京大学大学院理学系研究科名誉教授

学位: 理学博士(東京大学)
理学修士(東京大学)

J-GLOBAL ID: 200901052041105974
researchmap会員ID: 1000013812

研究キーワード

4

研究分野

3

経歴

21

1993年 - 1998年

東京大学大学院理学系研究科助教授
1993年 - 1998年

Associate Professor, Graduate School of
1998年

- 東京大学大学院理学系研究科教授
1998年

- Professor, Graduate School of Science, The
1996年 - 1997年

京都大学化学研究所客員助教授

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学歴

4

委員歴

5

MISC

156

"Synthesis, Structure, and Reactions os a Novel Triarylsilanol with a Bowl-Type Framework: A Silanol Extremely Resistant to Self-Condensation" "jointly authored"

Chem. Lett. 2001, 1258-1259 2001年
"Synthesis, Structure, and Reactions of the First Stable Aromatic S-Nitrosothiol Bearing a Novel Dendrimer-Type Steric Protection Group" "jointly authored"

Chem. Lett. 2001, 1204-1205 2001年
"Synthesis and Structure of a Novel Ladder-type Organobismuth Compound with Bismuth-Oxygen Interactions" "jointly authored"

Organometallics 20, 2440-2442 2001年
"Synthesis and Structure of 5-Carbaphosphatrane" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem. 168-169, 597-600 2001年
"Synthesis and Thermolysis of the Novel Ring Systems Containing Nitrogen and Tetracoordinate Selenium" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem. 168, 259-262 2001年
"Synthesis and Structure of a Tricoordinate 1,2-Iodoxetane" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem. 168, 141-144 2001年
"Unusual Products in Reactions Using Ethyldimesitylborane, Mesityllithium, and Carbonyl Compounds" "jointly authored"

Heteroatom Chem. 12, 354-357 2001年
"Formation and X-ray Crystallographic Analysis of a 1,2λ⁵-Oxaphosphol-5(2H)-one" "jointly authored"

Heteroatom Chem. 12, 282-286 2001年
"Synthesis and Reactions of Conformation Isomers of a Stable Selenenic Acid Bearing a Bridged Calix[6]arene Framework" "jointly authored"

Heteroatom Chem. 12, 195-197 2001年
"Reversible Photo-Control of the Coordination Number of Silicon in a Tetrafluorosilicate Bearing a 2-(Phenylazo)phenyl Group" "jointly authored"

J. Am. Chem. Soc. 123, 10778-10779 2001年
"The First Direct Oxidative Conversion of a Selenol to a Stable Selenenic Acid: Experimental Demonstration of Three Processes Included in the Catalytic Cycle of Glutathione Peroxidase" "jointly authored"

Org. Lett. 3, 3569-3572 2001年
"A Disilane Containing Two Heptacoordinate Silicone Atoms and Dithiocarboxylate Ligands" "jointly authored"

Angew. Chem. Int. Ed. 40, 3450-3452 2001年
"Conformational Mobility of the Calix[6]arenes with Allyl and Ethyl Groups on the Lower Rim" "jointly authored"

Bull. Chem. Soc. Jpn. 74, 2167-2174 2001年
"Structural Characterization of a Pentacoordinate Monohydrosilane with the Apical Si-H bond" "jointly authored"

Chem. Heterocyclic Compounds 2001, 1524-1525 2001年
"The First Isolable Pentacoordinate 1,2λ⁵-Azaphosphetine: Synthesis, X-ray Crystallographic Analysis, and Dynamic Behaviour" "jointly authored"

Chem. Commun. 2096-2097 2001年
"Synthesis, Structure, and Reactions os a Novel Triarylsilanol with a Bowl-Type Framework: A Silanol Extremely Resistant to Self-Condensation" "jointly authored"

Chem. Lett. 1258-1259 2001年
"Synthesis, Structure, and Reactions of the First Stable Aromatic S-Nitrosothiol Bearing a Novel Dendrimer-Type Steric Protection Group" "jointly authored"

Chem. Lett. 1204-1205 2001年
"Synthesis and Structure of a Novel Ladder-type Organobismuth Compound with Bismuth-Oxygen Interactions" "jointly authored"

Organometallics 20, 2440-2442 2001年
"Synthesis and Structure of 5-Carbaphosphatrane" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem. 168-169, 597-600 2001年
"Synthesis and Thermolysis of the Novel Ring Systems Containing Nitrogen and Tetracoordinate Selenium" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem. 168, 259-262 2001年
"Synthesis and Structure of a Tricoordinate 1,2-Iodoxetane" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem. 168, 141-144 2001年
"Unusual Products in Reactions Using Ethyldimesitylborane, Mesityllithium, and Carbonyl Compounds" "jointly authored"

Heteroatom Chem. 12, 354-357 2001年
"Formation and X-ray Crystallographic Analysis of a 1,2λ⁵-Oxaphosphol-5(2H)-one" "jointly authored"

Heteroatom Chem. 12, 282-286 2001年
"Synthesis and Reactions of Conformation Isomers of a Stable Selenenic Acid Bearing a Bridged Calix[6]arene Framework" "jointly authored"

Heteroatom Chem. 12, 195-197 2001年
Novel Ring System with a Se-O-N Linkage : Synthesis and Crystal Structure of the First 1, 2λ⁴, 5-Oxaselenazolidine jointed authored

Naokazu Kano, Nobuhito Nakanishi, Yuya Daicho, Takayuki Kawashima

Chem. Lett. (7) 610-611 2001年
5-Carbaphosphatranes : The First Main Group Atrane Bearing a 1-5 Covalent Bond jointed authored

J. Am. Chem. Soc. 123(14) 3387-3388 2001年
Synthesis and Structures of Azobenzenes Bearing Silyl, Germyl, and Stannyl Groups at 2-Position jointed authored

Naokazu Kano, Fuminori Komatsu, Takayuki Kawashima

Chem. Lett. (4) 338-339 2001年
Synthesis, Structure, and Reactions of a Tricoordinate 1, 2-Iodoxetane jointed authored

J. Am. Chem. Soc. 123(7) 1507-1508 2001年
Synthesis, Crystal Structure and Thermolysis of the First Tetracoordinate 1λ⁴, 2-Selenazetidines : Aziridine Formation Reaction from a Four-Membered Heterocycle Bearing Highly Coordinate Selenium jointed authored

Org. Lett. 3(5) 691-694 2001年
Synthesis and Thermolysis of Novel Spiroselenuranes Bearing Two Oxaselenetane Rings : Double Oxirane Formation Reactions from 1, 5-Dioxa-4λ⁴-selenaspiro[3.3]heptanes jointed authored

Chem. Commun. (5) 463-464 2001年
Synthesis and Crystal Structure of a Stable ┣DBS-nitrosothiol(/)-┫DB Bearing a Novel Steric Protection Group and of the Corresponding ┣DBS(/)-┫DB-nitrothiol jointed authored

Tetrahedron Lett. 41(44) 8479-8483 2000年
Synthesis, Structure, and Thermolysis of Pentacoordinate 1, 3, 2λ⁵-Oxazaphosphetidines : The Intermediates of Aza-Wittig Reactions jointed authored

Tetrahedron Lett. 41(27) 5237-5241 2000年
Structural Elucidation of 1, 3-Phenylenebis(methylene)-bridged Calix[6]arenes with Four Uncapped Hydroxy Groups jointed authored

Bull. Chem. Soc. Jpn. 73(8) 1893-1902 2000年
Small Ring Compounds Containing Highly Coordinate Group 14 Elements

J. Organomet. Chem. 611(1/2) 256-263 2000年
Crystal Structures and Solvate Formation of Two Conformationally Frozen Isomers of a Bridged Calix[6]arene jointed authored

J. Inclusion Phenomena and Macrocyclic Chem joint authored 36 117-122 2000年
Synthesis, Structure, and Redox Properties of a Quinone-Bridged Calix[6]arene jointed authored

Tetrahedron Lett. 41(6) 897-901 2000年
Desilylation-triggered Isomeriation of a Molecular Capsule from an Open-type to a Collapsed-type Isomer jointed authored

Tetrahedron Lett. 40(18) 3569-3572 1999年
Formation of a 1,3,2,4-Dioxadiborinanide, a Novel Bron-containing Heterocycle, by Hydrolysis of a Tetracoordinate 1,2-oxaboretanide and Its Crystal Structure jointed authored

Organometallics 18(24) 5180-5182 1999年
Definition and Design of Diagonalization Reactions : Reactions of 1,2-Heteraazetidine N-Oxides jointed authored

Tetrahedron Lett. 40(50) 8893-8896 1999年
Control Fators of Two Reaction Modes of Pentacoordinate 1,2-Oxasiletanides, the Peterson Reaction and Homo-Brook Rearrangement jointed authored

Kenji Naganuma, Takayuki Kawashima, Renji Okazaki

Chem. Lett (11) 1139-1140 1999年
Different Aggregating Properties of Two Conformationally Frozen Isomers of a Water-Soluble Bridged Calix[6]arene jointed authored

Shigehisa Akine, Kei Goto, Takayuki Kawashima, Renji Okazaki

Bull. Chem. Soc. Jpn 72(12) 2781-2783 1999年
Gauche Conformers Relatively Stabilized by the Hypercoordination jointed authored

Org. Lett 1(8) 1145-1147 1999年
Formation of a Borlyene by Photolysis of an Overcrowded Bis(methylseleno)borane jointed authored

Tetrahedron Lett 40(30) 5557-5560 1999年
Synthesis of the First Stable Pentacoordinate 1,2-Thiaphosphetene jointed authored

Phosphorus, Sulfur, and Silicon 144-146,149-152 1999年
Stable Telluroketones : Synthesis and Chracterization

Mao Minoura, Takayuki Kawashima, Norihiro Tokitoh, Renji Okazaki

Phosphorus, Sulfur, and Silicon jointed authored 136/138(1) 549-552 1998年
Synthesis of Tetracoordinate 1,2-Oxaselenetanes and Their Oxirance Formation Reaction jointed authored

Phosphorus, Sulfur, and Silicon 136-138 501-504 1998年
Novel Synthetic Route to Isolable Pentacoordinate 1,2-Oxaphosphetanes and Mechanism of Their Thermolysis, the Second Step of the Wittig Reaction(correction) jointed authored

J. Am. Chem. Soc 120 6848 1998年
Synthesis, Structure, and Thermolysis of a 3-Methoxycarbonyl-1,2λ⁵-oxaphosphetane(corrigenda) jointed authored

Angew. Chem, Int. Ed. Engl 37 1606 1998年
"The Olefin Synthesis from β-Hydroxyalkylphosphonates Induced by Fluorides or Relatively Weak Bases" "jointly authored"

Takayuki Kawashima, Takafumi Ishii, Naoki Inamoto, Norihiro Tokitoh, Renji Okazaki

Bull. Chem. Soc. Jpn. 71(1) 209-219 1998年
"Generation and Decomposition of a Pentacoordinate Spirobis[1,2-oxasiletanide]" "jointly authored"

Organometallics 17(3) 367-372 1998年

書籍等出版物

11

"Modern Carbonyl 01efination"

Wiley-VCH, 2004年
「21世紀の有機ケイ素化学―機能性物質科学の宝庫―」

シーエムシー出版 2004年
「有機金属反応剤ハンドブック」

化学同人 2003年
"Four-membered Rings with 1 Phosphorus Atom" "jointly authored"

Phosphorus-Carbon Heterocyclic Chemistry: The Rise of a New Domain, Pergamon 2001年
"Four-membered Rings with 1 Phosphorus Atom" "jointly authored" Phosphorus-Carbon Heterocyclic Chemistry: The Rise of a New

Domain, Pergamon 2001年

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所属学協会

6

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共同研究・競争的資金等の研究課題

6

斬新な特定位置占拠型配位子の設計と高配位典型元素化合物の創製

科学研究費補助金 2003年 - 2007年
Development of novel ligands occupying the specified position and their application to the synthesis of new hypervalent compounds

Grant-in-Aid for Scientific Research 2003年 - 2007年
ヘテロ原子の特徴を活用した新規反応の開発

科学研究費補助金 1990年
高配位典型元素を有するヘテロ原子化合物の合成と反応

科学研究費補助金 1990年
Development of Novel Reactions Utilizing Characteristics of Heteroatoms

Grant-in-Aid for Scientific Research 1990年

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