Curriculum Vitaes

Takayuki Kawashima

(川島隆幸)

Profile Information

Affiliation: Visiting Professor, Faculty of Science, Gakushuin University
Professor Emeritus, Graduate School of Science, The University of Tokyo

Degree: (BLANK)(The University of Tokyo)
(BLANK)(The University of Tokyo)

J-GLOBAL ID: 200901052041105974
researchmap Member ID: 1000013812

Research Interests

4

Research Areas

3

Research History

21

1993 - 1998

Graduate School of Science, The University of Tokyo
1993 - 1998

Associate Professor, Graduate School of
1998

- 東京大学大学院理学系研究科教授
1998

- Professor, Graduate School of Science, The
1996 - 1997

Institute for Chemical Research, Kyoto University

Education

4

- 1974

The University of Tokyo
- 1974

Chemistry, Graduate School of Science, The University of Tokyo
- 1969

Faculty of Science, The University of Tokyo
- 1969

Chemistry, Faculty of Science, The University of Tokyo

Committee Memberships

5

Misc.

156

"Synthesis, Structure, and Reactions os a Novel Triarylsilanol with a Bowl-Type Framework: A Silanol Extremely Resistant to Self-Condensation" "jointly authored"

Chem. Lett., 2001, 1258-1259, 2001
"Synthesis, Structure, and Reactions of the First Stable Aromatic S-Nitrosothiol Bearing a Novel Dendrimer-Type Steric Protection Group" "jointly authored"

Chem. Lett., 2001, 1204-1205, 2001
"Synthesis and Structure of a Novel Ladder-type Organobismuth Compound with Bismuth-Oxygen Interactions" "jointly authored"

Organometallics, 20, 2440-2442, 2001
"Synthesis and Structure of 5-Carbaphosphatrane" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem., 168-169, 597-600, 2001
"Synthesis and Thermolysis of the Novel Ring Systems Containing Nitrogen and Tetracoordinate Selenium" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem., 168, 259-262, 2001
"Synthesis and Structure of a Tricoordinate 1,2-Iodoxetane" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem., 168, 141-144, 2001
"Unusual Products in Reactions Using Ethyldimesitylborane, Mesityllithium, and Carbonyl Compounds" "jointly authored"

Heteroatom Chem., 12, 354-357, 2001
"Formation and X-ray Crystallographic Analysis of a 1,2λ⁵-Oxaphosphol-5(2H)-one" "jointly authored"

Heteroatom Chem., 12, 282-286, 2001
"Synthesis and Reactions of Conformation Isomers of a Stable Selenenic Acid Bearing a Bridged Calix[6]arene Framework" "jointly authored"

Heteroatom Chem., 12, 195-197, 2001
"Reversible Photo-Control of the Coordination Number of Silicon in a Tetrafluorosilicate Bearing a 2-(Phenylazo)phenyl Group" "jointly authored"

J. Am. Chem. Soc., 123, 10778-10779, 2001
"The First Direct Oxidative Conversion of a Selenol to a Stable Selenenic Acid: Experimental Demonstration of Three Processes Included in the Catalytic Cycle of Glutathione Peroxidase" "jointly authored"

Org. Lett., 3, 3569-3572, 2001
"A Disilane Containing Two Heptacoordinate Silicone Atoms and Dithiocarboxylate Ligands" "jointly authored"

Angew. Chem. Int. Ed., 40, 3450-3452, 2001
"Conformational Mobility of the Calix[6]arenes with Allyl and Ethyl Groups on the Lower Rim" "jointly authored"

Bull. Chem. Soc. Jpn., 74, 2167-2174, 2001
"Structural Characterization of a Pentacoordinate Monohydrosilane with the Apical Si-H bond" "jointly authored"

Chem. Heterocyclic Compounds, 2001, 1524-1525, 2001
"The First Isolable Pentacoordinate 1,2λ⁵-Azaphosphetine: Synthesis, X-ray Crystallographic Analysis, and Dynamic Behaviour" "jointly authored"

Chem. Commun., 2096-2097, 2001
"Synthesis, Structure, and Reactions os a Novel Triarylsilanol with a Bowl-Type Framework: A Silanol Extremely Resistant to Self-Condensation" "jointly authored"

Chem. Lett., 1258-1259, 2001
"Synthesis, Structure, and Reactions of the First Stable Aromatic S-Nitrosothiol Bearing a Novel Dendrimer-Type Steric Protection Group" "jointly authored"

Chem. Lett., 1204-1205, 2001
"Synthesis and Structure of a Novel Ladder-type Organobismuth Compound with Bismuth-Oxygen Interactions" "jointly authored"

Organometallics, 20, 2440-2442, 2001
"Synthesis and Structure of 5-Carbaphosphatrane" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem., 168-169, 597-600, 2001
"Synthesis and Thermolysis of the Novel Ring Systems Containing Nitrogen and Tetracoordinate Selenium" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem., 168, 259-262, 2001
"Synthesis and Structure of a Tricoordinate 1,2-Iodoxetane" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem., 168, 141-144, 2001
"Unusual Products in Reactions Using Ethyldimesitylborane, Mesityllithium, and Carbonyl Compounds" "jointly authored"

Heteroatom Chem., 12, 354-357, 2001
"Formation and X-ray Crystallographic Analysis of a 1,2λ⁵-Oxaphosphol-5(2H)-one" "jointly authored"

Heteroatom Chem., 12, 282-286, 2001
"Synthesis and Reactions of Conformation Isomers of a Stable Selenenic Acid Bearing a Bridged Calix[6]arene Framework" "jointly authored"

Heteroatom Chem., 12, 195-197, 2001
Novel Ring System with a Se-O-N Linkage : Synthesis and Crystal Structure of the First 1, 2λ⁴, 5-Oxaselenazolidine jointed authored

Naokazu Kano, Nobuhito Nakanishi, Yuya Daicho, Takayuki Kawashima

Chem. Lett., (7) 610-611, 2001
5-Carbaphosphatranes : The First Main Group Atrane Bearing a 1-5 Covalent Bond jointed authored

J. Am. Chem. Soc., 123(14) 3387-3388, 2001
Synthesis and Structures of Azobenzenes Bearing Silyl, Germyl, and Stannyl Groups at 2-Position jointed authored

Naokazu Kano, Fuminori Komatsu, Takayuki Kawashima

Chem. Lett., (4) 338-339, 2001
Synthesis, Structure, and Reactions of a Tricoordinate 1, 2-Iodoxetane jointed authored

J. Am. Chem. Soc., 123(7) 1507-1508, 2001
Synthesis, Crystal Structure and Thermolysis of the First Tetracoordinate 1λ⁴, 2-Selenazetidines : Aziridine Formation Reaction from a Four-Membered Heterocycle Bearing Highly Coordinate Selenium jointed authored

Org. Lett., 3(5) 691-694, 2001
Synthesis and Thermolysis of Novel Spiroselenuranes Bearing Two Oxaselenetane Rings : Double Oxirane Formation Reactions from 1, 5-Dioxa-4λ⁴-selenaspiro[3.3]heptanes jointed authored

Chem. Commun., (5) 463-464, 2001
Synthesis and Crystal Structure of a Stable ┣DBS-nitrosothiol(/)-┫DB Bearing a Novel Steric Protection Group and of the Corresponding ┣DBS(/)-┫DB-nitrothiol jointed authored

Tetrahedron Lett., 41(44) 8479-8483, 2000
Synthesis, Structure, and Thermolysis of Pentacoordinate 1, 3, 2λ⁵-Oxazaphosphetidines : The Intermediates of Aza-Wittig Reactions jointed authored

Tetrahedron Lett., 41(27) 5237-5241, 2000
Structural Elucidation of 1, 3-Phenylenebis(methylene)-bridged Calix[6]arenes with Four Uncapped Hydroxy Groups jointed authored

Bull. Chem. Soc. Jpn., 73(8) 1893-1902, 2000
Small Ring Compounds Containing Highly Coordinate Group 14 Elements

J. Organomet. Chem., 611(1/2) 256-263, 2000
Crystal Structures and Solvate Formation of Two Conformationally Frozen Isomers of a Bridged Calix[6]arene jointed authored

J. Inclusion Phenomena and Macrocyclic Chem joint authored, 36 117-122, 2000
Synthesis, Structure, and Redox Properties of a Quinone-Bridged Calix[6]arene jointed authored

Tetrahedron Lett., 41(6) 897-901, 2000
Desilylation-triggered Isomeriation of a Molecular Capsule from an Open-type to a Collapsed-type Isomer jointed authored

Tetrahedron Lett., 40(18) 3569-3572, 1999
Formation of a 1,3,2,4-Dioxadiborinanide, a Novel Bron-containing Heterocycle, by Hydrolysis of a Tetracoordinate 1,2-oxaboretanide and Its Crystal Structure jointed authored

Organometallics, 18(24) 5180-5182, 1999
Definition and Design of Diagonalization Reactions : Reactions of 1,2-Heteraazetidine N-Oxides jointed authored

Tetrahedron Lett., 40(50) 8893-8896, 1999
Control Fators of Two Reaction Modes of Pentacoordinate 1,2-Oxasiletanides, the Peterson Reaction and Homo-Brook Rearrangement jointed authored

Kenji Naganuma, Takayuki Kawashima, Renji Okazaki

Chem. Lett, (11) 1139-1140, 1999
Different Aggregating Properties of Two Conformationally Frozen Isomers of a Water-Soluble Bridged Calix[6]arene jointed authored

Shigehisa Akine, Kei Goto, Takayuki Kawashima, Renji Okazaki

Bull. Chem. Soc. Jpn, 72(12) 2781-2783, 1999
Gauche Conformers Relatively Stabilized by the Hypercoordination jointed authored

Org. Lett, 1(8) 1145-1147, 1999
Formation of a Borlyene by Photolysis of an Overcrowded Bis(methylseleno)borane jointed authored

Tetrahedron Lett, 40(30) 5557-5560, 1999
Synthesis of the First Stable Pentacoordinate 1,2-Thiaphosphetene jointed authored

Phosphorus, Sulfur, and Silicon, 144-146,149-152, 1999
Stable Telluroketones : Synthesis and Chracterization

Mao Minoura, Takayuki Kawashima, Norihiro Tokitoh, Renji Okazaki

Phosphorus, Sulfur, and Silicon jointed authored, 136/138(1) 549-552, 1998
Synthesis of Tetracoordinate 1,2-Oxaselenetanes and Their Oxirance Formation Reaction jointed authored

Phosphorus, Sulfur, and Silicon, 136-138 501-504, 1998
Novel Synthetic Route to Isolable Pentacoordinate 1,2-Oxaphosphetanes and Mechanism of Their Thermolysis, the Second Step of the Wittig Reaction(correction) jointed authored

J. Am. Chem. Soc, 120 6848, 1998
Synthesis, Structure, and Thermolysis of a 3-Methoxycarbonyl-1,2λ⁵-oxaphosphetane(corrigenda) jointed authored

Angew. Chem, Int. Ed. Engl, 37 1606, 1998
"The Olefin Synthesis from β-Hydroxyalkylphosphonates Induced by Fluorides or Relatively Weak Bases" "jointly authored"

Takayuki Kawashima, Takafumi Ishii, Naoki Inamoto, Norihiro Tokitoh, Renji Okazaki

Bull. Chem. Soc. Jpn., 71(1) 209-219, 1998
"Generation and Decomposition of a Pentacoordinate Spirobis[1,2-oxasiletanide]" "jointly authored"

Organometallics, 17(3) 367-372, 1998

Books and Other Publications

11

"Modern Carbonyl 01efination"

Wiley-VCH,, 2004
「21世紀の有機ケイ素化学―機能性物質科学の宝庫―」

シーエムシー出版, 2004
「有機金属反応剤ハンドブック」

化学同人, 2003
"Four-membered Rings with 1 Phosphorus Atom" "jointly authored"

Phosphorus-Carbon Heterocyclic Chemistry: The Rise of a New Domain, Pergamon, 2001
"Four-membered Rings with 1 Phosphorus Atom" "jointly authored" Phosphorus-Carbon Heterocyclic Chemistry: The Rise of a New

Domain, Pergamon, 2001

Professional Memberships

6

Research Projects

6

斬新な特定位置占拠型配位子の設計と高配位典型元素化合物の創製

科学研究費補助金, 2003 - 2007
Development of novel ligands occupying the specified position and their application to the synthesis of new hypervalent compounds

Grant-in-Aid for Scientific Research, 2003 - 2007
ヘテロ原子の特徴を活用した新規反応の開発

科学研究費補助金, 1990
高配位典型元素を有するヘテロ原子化合物の合成と反応

科学研究費補助金, 1990
Development of Novel Reactions Utilizing Characteristics of Heteroatoms

Grant-in-Aid for Scientific Research, 1990

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