Curriculum Vitaes

Takayuki Kawashima

(川島隆幸)

Profile Information

Affiliation: Visiting Professor, Faculty of Science, Gakushuin University
Professor Emeritus, Graduate School of Science, The University of Tokyo

Degree: (BLANK)(The University of Tokyo)
(BLANK)(The University of Tokyo)

J-GLOBAL ID: 200901052041105974
researchmap Member ID: 1000013812

Research Interests

4

Research Areas

3

Research History

21

1993 - 1998

Graduate School of Science, The University of Tokyo
1993 - 1998

Associate Professor, Graduate School of
1998

- 東京大学大学院理学系研究科教授
1998

- Professor, Graduate School of Science, The
1996 - 1997

Institute for Chemical Research, Kyoto University

Education

4

- 1974

The University of Tokyo
- 1974

Chemistry, Graduate School of Science, The University of Tokyo
- 1969

Faculty of Science, The University of Tokyo
- 1969

Chemistry, Faculty of Science, The University of Tokyo

Committee Memberships

5

Misc.

156

「ウイッティッヒ反応」

化学, 52 39-41, 1997
"Formation of a Pentacoordinate 1,2-Oxastannetanide by Novel Base-Induced Rearrangement of a Bis(β-hydroxyalkyl)stannane" "jointly authored"

Phosphorus, Sulfur, and Silicon, 124&125 513-516, 1997
"Synthesis and Double Olefin Extrusion of 2,2,6,6-Tetraaryl-1,5-dioxa-4λ⁵-phospha-spiro[3.3]heptanes" "jointly authored"

Phosphorus, Sulfur, and Silicon, 124&125 379-386, 1997
"An Endohedral Simple Enol : The First Isolation of a β-Unsubstituted Simple Enol Utilizing a Lantern-Shaped Molecular Framework" "jointly authored"

J. Am. Chem. Soc., 119(13) 3195-3196, 1997
"Synthesis, Structure, and Double Olefin Extrusion of All Theree Diastereomers of 2,2,6,6-Tetrakis(4-chlorophenyl)-3,7-dimethyl-4-phenyl-1,5-dioxa-4λ⁵-phosphaspiro[3.3]heptane" "jointly authored"

Angew. Chem. Int. Ed. Engl., 36(22) 2500-2502, 1997
"Novel reactivity of tetracoordinate 1,2-λ⁴-oxaselenetanes : oxirane formation reaction with retention of configuration" "jointly authored"

Chem. Commun., (17) 1671-1672, 1997
"△³-1,3,4-Telluradiazolines, a Novel Tellurium Containing Heterocycle : One-pot Synthesis, Structure, and Reactivity" "jointly authored"

Tetrahedron, 53(24) 8137-8148, 1997
"The First Isolation of a Telluroketone and Its Reversible Dimerization" "jointly authored"

Tetrahedron Lett., 38(14) 2501-2504, 1997
"Synthesis and Thermolysis of Hexacoordinate 1,2-Oxaphosphetanides" "jointly authored"

Tetrahedron Lett., 38(4) 551-554, 1997
Tandem Peterson-Michael reaction using alpha-silylalkylphosphine chalcogenides and Horner-Emmons reaction of in situ generated alpha-carban-ions of its products

T Kawashima, M Nakamura, N Inamoto

HETEROCYCLES, 44 487-507, Jan, 1997
"Wittig Reaction"

Chemistry, 52 39-41, 1997
Synthesis and structures of the intermediates of the Wittig, Peterson, and their related reactions

T Kawashima

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 54(8) 696-707, Aug, 1996
「Wittig反応、Peterson反応および関連する反応中間体の合成と反応」

川島隆幸

有機合成化学協会誌, 54(8) 696-707, 1996
"Four-membered Rings with One Phosphorus, Arsenic, Anrimony, or Bismuth Atom" "jointly authored"

Comprehensive Heterocyclic Chemistry II, Elsevier Science, Oxford, 1B 833-866, 1996
"Experimental and Theoretical Evidence for Oxirane Formation Reaction of Pentacoordinate 1,2λ⁶-Oxathietanes with Retention of Configuration" "jointly authored"

J. Am. Chem. Soc., 118(49) 12455-12456, 1996
"Synthesis and Reactions of the Intermediates of the Wittig, Peterson, and their Related Reactions" "jointly authored"

Synlett., (7) 600-608, 1996
"Syntheses, Structures, and Thermolyses of Four-Membered Heterocycles Containing a Highly Coordinate Main Group Element" "jointly authored"

Zhurn. Org. Khim., 32 305-313, 1996
"Synthesis, Structure, and Thermolysis of N-Apical 1,2λ⁵-Azaphosphetidines with a Pentacoordinate P Center and the First Observation of Their N-Equatorial Pseudorotamers"

Angew. Chem., Int. Ed. Engl., 35(10) 1096-1098, 1996
"Synthesis, Stereochemistry, and Thermolysis of β-Aminoalkylboranes"

Takayuki Kawashima, Naoko Yamashita, Renji Okazaki

Chem. Lett., (3) 213-214, 1996
"Synthesis, Crystal Structure, and Thermolysis of a Pentacoordinate 1,2λ⁶-Oxatheitane : An Intermediate of the Corey-Chaykovsky of Oxosulfonium Ylides? "

<J. Am. Chem. Soc.>, 118(3) 697-698, 1996
"Synthesis and Thermolysis of Pentacoordinate 1,2-Azaphosphetidines"

Phosphorus, Sulfur and Silicon, 109-110,489-492, 1996
"Cycloaddition and Oxidation of a Stable Thioaldehyde : (2,4,6-Trit-┣DBt(/)-┫DB-butyl)thiobenzaldehyde"

Soichiro Watanabe, Toshio Yamamoto, Takayuki Kawashima, Naoki Inamoto, Renji Okazaki

Bull. Chem. Soc. Jpn., 69(3) 719-724, 1996
"Weak Coordination of a Telluroketone in a η¹-1Mode Complex : Synthesis and Characterization of Pentacarbonyl(1,1,3,3-tetramethylindantellone)tungsten"

Chem. Commun., (2) 123-124, 1996
SYNTHESIS AND CRYSTAL-STRUCTURE OF A PENTACOORDINATE 1,2-OXAGERMETANIDE

T KAWASHIMA, Y NISHIWAKI, R OKAZAKI

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 499(1-2) 143-146, Sep, 1995
GENERATION OF METAL PHOSPHINITES BY THE REACTION OF SE-ALKYL PHOSPHINOSELENOATES WITH ORGANOMETALLICS AND ITS APPLICATION TO THE SYNTHESIS OF OPTICALLY-ACTIVE ORGANOPHOSPHORUS COMPOUNDS

T KAWASHIMA, H IWANAGA, R OKAZAKI

HETEROATOM CHEMISTRY, 6(3) 235-240, May, 1995
"Thermolysis of β-Siloxyalkylboranes : Formation of Alkenes and/or Silyl Enol Ethers"

Chem. Lett., (12) 1107-1108, 1995
"Synthesis of Novel Lantern-shaped Molecules Based on Resorcin[4]arene and ┣DBm(/)-┫DB-Terphenyl Units"

Tetrahedron Lett., 36,7677-7680, 1995
"Synthesis, Structure and Thermolysis of Tetracoordinate 1,2-Oxaboretanide : An Intermediate of the Boron-Witting Reaction under Basic Conditions".

┣DBJ. Am. Chem. Soc. (/)-┫DB, (117) 6142, 1995
REACTIONS OF (2,4,6-TRI-T-BUTYL)THIOBENZALDEHYDE WITH DIAZO-COMPOUNDS - SYNTHESIS AND REACTIONS OF STERICALLY CONGESTED THIIRANES

S WATANABE, T KAWASHIMA, N TOKITOH, R OKAZAKI

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 68(5) 1437-1448, 1995
"Syntheses, Structures, and Thermolyses of Tetracoordinate 1,2λ⁴-Oxathietanes"

<Phosphorus, Sulfur and Silicon>, (95-96) 439, 1994
"Synthesis, Structure, and Reactivity of 1,4,2-Oxatellurazole : a Novel Tellurium-Containing Heterocycle"

<Phosphorus, Sulfur and Silicon>, (93-94) 403, 1994
"Synthesis, Structure, and Thermolysis of a Tetracoordinate 1,2λ⁴-Oxathietane"

<Angew. Chem. Int. Ed. Engl.>, (33) 2094, 1994
"The Witting Rearrangement of Chiral ┣DBS(/)-┫DB-Methyl Phosphinothioates Promoted by Direct Deprotonation with Lithium Dialkylamides"

Takayuki Kawashima, Satoshi Kojima, Naoki Inamoto

<Bull. Chem. Soc. Jpn.>, 67(9) 2603-2606, 1994
"Structure and Thermolysis of a 1,4,2-Oxatellurazole, a Novel Tellurium Containing Heterocycle"

<Chem. Lett.>, (1994) 1691, 1994
"Synthesis, Isolation, and Thermolysis of Tetracoordinate 1,2-Oxaphosphetanes Stabilized by Steric Protection"

<Chem. Lett.>, (1994) 1487, 1994
"Intramolecular Dehydration of β-Hydroxyalkylphosphonic Acid Monoesters. A Novel Type of Olefin Formation"

<Chem. Lett.>, (1994) 1483, 1994
"Reaction of 2,4,6-Tri-┣DBt(/)-┫DB-butylselenobenzaldegyde with Sterically Crowded Diazo Compounds. Formation of Seleniranes"

<Chem. Lett.>, (1994) 1289, 1994
"Synthesis, Structure, and Thermolysis of a 1,5-Dioxa-4λ⁵-phosphaspiro〔3.3〕heptane : a Novel Pentacoordinate 1,2-Oxaphosphetane"

<J. Am. Chem. Soc.>, (116) 4509, 1994
"Synthesis and Crystal Structure of an Intermediate of the Germanium-Peterson Reaction"

J. Org. Chem., 59(2) 491-493, 1994
Crystal Structure and Reactivity of a Pentacoordinate 1,2-Oxastannetanide : An Intermediate of the Tin-Peterson Reaction

J. Am. Chem. Soc., 115(6) 2507-2508, 1993
Synthesis, Structure, and Thermolysis of a 3-Methoxycarbonyl-1,2λ⁵-oxaphosphetane

Angew. Chem. , Int. Ed. Engl., 32(6) 869-870, 1993
Synthesis of Δ³-1,3,4-Telluradiazolines, a Novel Tellurium-Containing Heterocycle

Chem. Lett., (6) 1047-1048, 1993
1,1,3,3-Tetramethylindantellone, the First Telluroketone Stable in Solution

J. Am. Chem. Soc., 115(15) 7019-7020, 1993
Synthesis of Optically Active Phosphorus Compounds via Metal Phosphinite Generated by Reaction of Optically Active Selenophosphinates with Phenyllithium

Takayuki Kawashima, Hiroki Iwanaga, Renji Okazaki

Chem. Lett., (9) 1531-1532, 1993
Synthesis, Structures, and Thermolyses of Tetracoordinate 1,2-Oxaselenetanes

J. Am. Chem. Soc., 115(22) 10434-10435, 1993
Synthesis and X-ray Crystallographic Analysis of Pentacoordinate 1, 2-Oxasiletanides, Intermediates of the Peterson Reaction

J. Am. Chem. Soc, 114(19) 7598-7599, 1992
Tandem Peterson-Michael Reaction Using α-Silylalkylphosphine Chalocogenides and Horner-Emmons Reaction

Phosphorus, Sulfur, and Silicon, 69 293, 1992
The Phospha-Cope Rearrangement of 3-Phospha-1,5-hexadiene Dirivatives Bearing a Hydroxyl Group

Takayuki Kawashima, Dae Jong Park, Shinobu Murata, Renji Okazaki, Naoki Inamoto

Chemistry Letters, (8) 1607-1610, 1992
Novel Synthetic Route to Isolable Pentacoordinate 1,2-Oxaphosphetanes and Mechanism of Their Thermolysis, the Second Step of the Wittig Reaction

Journal of the American Chemical Society, 114(10) 4008-4010, 1992
The 1,3-Diastereoselective Synthesis of 2-Hydroxyalkyl-phosphine Oxides Based on a Chiral Phosphorus Center

Phosphorus, Sulfur, and Silicon, 60 21, 1991

Books and Other Publications

11

"Modern Carbonyl 01efination"

Wiley-VCH,, 2004
「21世紀の有機ケイ素化学―機能性物質科学の宝庫―」

シーエムシー出版, 2004
「有機金属反応剤ハンドブック」

化学同人, 2003
"Four-membered Rings with 1 Phosphorus Atom" "jointly authored"

Phosphorus-Carbon Heterocyclic Chemistry: The Rise of a New Domain, Pergamon, 2001
"Four-membered Rings with 1 Phosphorus Atom" "jointly authored" Phosphorus-Carbon Heterocyclic Chemistry: The Rise of a New

Domain, Pergamon, 2001

Professional Memberships

6

Research Projects

6

斬新な特定位置占拠型配位子の設計と高配位典型元素化合物の創製

科学研究費補助金, 2003 - 2007
Development of novel ligands occupying the specified position and their application to the synthesis of new hypervalent compounds

Grant-in-Aid for Scientific Research, 2003 - 2007
ヘテロ原子の特徴を活用した新規反応の開発

科学研究費補助金, 1990
高配位典型元素を有するヘテロ原子化合物の合成と反応

科学研究費補助金, 1990
Development of Novel Reactions Utilizing Characteristics of Heteroatoms

Grant-in-Aid for Scientific Research, 1990

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