研究者業績

川島隆幸

カワシマタカユキ (Takayuki Kawashima)

基本情報

所属: 学習院大学理学部客員教授
東京大学大学院理学系研究科名誉教授

学位: 理学博士(東京大学)
理学修士(東京大学)

J-GLOBAL ID: 200901052041105974
researchmap会員ID: 1000013812

研究キーワード

4

研究分野

3

経歴

21

1993年 - 1998年

東京大学大学院理学系研究科助教授
1993年 - 1998年

Associate Professor, Graduate School of
1998年

- 東京大学大学院理学系研究科教授
1998年

- Professor, Graduate School of Science, The
1996年 - 1997年

京都大学化学研究所客員助教授

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学歴

4

委員歴

5

MISC

156

「ウイッティッヒ反応」

化学 52 39-41 1997年
"Formation of a Pentacoordinate 1,2-Oxastannetanide by Novel Base-Induced Rearrangement of a Bis(β-hydroxyalkyl)stannane" "jointly authored"

Phosphorus, Sulfur, and Silicon 124&125 513-516 1997年
"Synthesis and Double Olefin Extrusion of 2,2,6,6-Tetraaryl-1,5-dioxa-4λ⁵-phospha-spiro[3.3]heptanes" "jointly authored"

Phosphorus, Sulfur, and Silicon 124&125 379-386 1997年
"An Endohedral Simple Enol : The First Isolation of a β-Unsubstituted Simple Enol Utilizing a Lantern-Shaped Molecular Framework" "jointly authored"

J. Am. Chem. Soc. 119(13) 3195-3196 1997年
"Synthesis, Structure, and Double Olefin Extrusion of All Theree Diastereomers of 2,2,6,6-Tetrakis(4-chlorophenyl)-3,7-dimethyl-4-phenyl-1,5-dioxa-4λ⁵-phosphaspiro[3.3]heptane" "jointly authored"

Angew. Chem. Int. Ed. Engl. 36(22) 2500-2502 1997年
"Novel reactivity of tetracoordinate 1,2-λ⁴-oxaselenetanes : oxirane formation reaction with retention of configuration" "jointly authored"

Chem. Commun. (17) 1671-1672 1997年
"△³-1,3,4-Telluradiazolines, a Novel Tellurium Containing Heterocycle : One-pot Synthesis, Structure, and Reactivity" "jointly authored"

Tetrahedron 53(24) 8137-8148 1997年
"The First Isolation of a Telluroketone and Its Reversible Dimerization" "jointly authored"

Tetrahedron Lett. 38(14) 2501-2504 1997年
"Synthesis and Thermolysis of Hexacoordinate 1,2-Oxaphosphetanides" "jointly authored"

Tetrahedron Lett. 38(4) 551-554 1997年
Tandem Peterson-Michael reaction using alpha-silylalkylphosphine chalcogenides and Horner-Emmons reaction of in situ generated alpha-carban-ions of its products

T Kawashima, M Nakamura, N Inamoto

HETEROCYCLES 44 487-507 1997年1月
"Wittig Reaction"

Chemistry 52 39-41 1997年
Synthesis and structures of the intermediates of the Wittig, Peterson, and their related reactions

T Kawashima

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN 54(8) 696-707 1996年8月
「Wittig反応、Peterson反応および関連する反応中間体の合成と反応」

川島隆幸

有機合成化学協会誌 54(8) 696-707 1996年
"Four-membered Rings with One Phosphorus, Arsenic, Anrimony, or Bismuth Atom" "jointly authored"

Comprehensive Heterocyclic Chemistry II, Elsevier Science, Oxford 1B 833-866 1996年
"Experimental and Theoretical Evidence for Oxirane Formation Reaction of Pentacoordinate 1,2λ⁶-Oxathietanes with Retention of Configuration" "jointly authored"

J. Am. Chem. Soc. 118(49) 12455-12456 1996年
"Synthesis and Reactions of the Intermediates of the Wittig, Peterson, and their Related Reactions" "jointly authored"

Synlett. (7) 600-608 1996年
"Syntheses, Structures, and Thermolyses of Four-Membered Heterocycles Containing a Highly Coordinate Main Group Element" "jointly authored"

Zhurn. Org. Khim. 32 305-313 1996年
"Synthesis, Structure, and Thermolysis of N-Apical 1,2λ⁵-Azaphosphetidines with a Pentacoordinate P Center and the First Observation of Their N-Equatorial Pseudorotamers"

Angew. Chem., Int. Ed. Engl. 35(10) 1096-1098 1996年
"Synthesis, Stereochemistry, and Thermolysis of β-Aminoalkylboranes"

Takayuki Kawashima, Naoko Yamashita, Renji Okazaki

Chem. Lett. (3) 213-214 1996年
"Synthesis, Crystal Structure, and Thermolysis of a Pentacoordinate 1,2λ⁶-Oxatheitane : An Intermediate of the Corey-Chaykovsky of Oxosulfonium Ylides? "

<J. Am. Chem. Soc.> 118(3) 697-698 1996年
"Synthesis and Thermolysis of Pentacoordinate 1,2-Azaphosphetidines"

Phosphorus, Sulfur and Silicon 109-110,489-492 1996年
"Cycloaddition and Oxidation of a Stable Thioaldehyde : (2,4,6-Trit-┣DBt(/)-┫DB-butyl)thiobenzaldehyde"

Soichiro Watanabe, Toshio Yamamoto, Takayuki Kawashima, Naoki Inamoto, Renji Okazaki

Bull. Chem. Soc. Jpn. 69(3) 719-724 1996年
"Weak Coordination of a Telluroketone in a η¹-1Mode Complex : Synthesis and Characterization of Pentacarbonyl(1,1,3,3-tetramethylindantellone)tungsten"

Chem. Commun. (2) 123-124 1996年
SYNTHESIS AND CRYSTAL-STRUCTURE OF A PENTACOORDINATE 1,2-OXAGERMETANIDE

T KAWASHIMA, Y NISHIWAKI, R OKAZAKI

JOURNAL OF ORGANOMETALLIC CHEMISTRY 499(1-2) 143-146 1995年9月
GENERATION OF METAL PHOSPHINITES BY THE REACTION OF SE-ALKYL PHOSPHINOSELENOATES WITH ORGANOMETALLICS AND ITS APPLICATION TO THE SYNTHESIS OF OPTICALLY-ACTIVE ORGANOPHOSPHORUS COMPOUNDS

T KAWASHIMA, H IWANAGA, R OKAZAKI

HETEROATOM CHEMISTRY 6(3) 235-240 1995年5月
"Thermolysis of β-Siloxyalkylboranes : Formation of Alkenes and/or Silyl Enol Ethers"

Chem. Lett. (12) 1107-1108 1995年
"Synthesis of Novel Lantern-shaped Molecules Based on Resorcin[4]arene and ┣DBm(/)-┫DB-Terphenyl Units"

Tetrahedron Lett. 36,7677-7680 1995年
"Synthesis, Structure and Thermolysis of Tetracoordinate 1,2-Oxaboretanide : An Intermediate of the Boron-Witting Reaction under Basic Conditions".

┣DBJ. Am. Chem. Soc. (/)-┫DB (117) 6142 1995年
REACTIONS OF (2,4,6-TRI-T-BUTYL)THIOBENZALDEHYDE WITH DIAZO-COMPOUNDS - SYNTHESIS AND REACTIONS OF STERICALLY CONGESTED THIIRANES

S WATANABE, T KAWASHIMA, N TOKITOH, R OKAZAKI

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 68(5) 1437-1448 1995年
"Syntheses, Structures, and Thermolyses of Tetracoordinate 1,2λ⁴-Oxathietanes"

<Phosphorus, Sulfur and Silicon> (95-96) 439 1994年
"Synthesis, Structure, and Reactivity of 1,4,2-Oxatellurazole : a Novel Tellurium-Containing Heterocycle"

<Phosphorus, Sulfur and Silicon> (93-94) 403 1994年
"Synthesis, Structure, and Thermolysis of a Tetracoordinate 1,2λ⁴-Oxathietane"

<Angew. Chem. Int. Ed. Engl.> (33) 2094 1994年
"The Witting Rearrangement of Chiral ┣DBS(/)-┫DB-Methyl Phosphinothioates Promoted by Direct Deprotonation with Lithium Dialkylamides"

Takayuki Kawashima, Satoshi Kojima, Naoki Inamoto

<Bull. Chem. Soc. Jpn.> 67(9) 2603-2606 1994年
"Structure and Thermolysis of a 1,4,2-Oxatellurazole, a Novel Tellurium Containing Heterocycle"

<Chem. Lett.> (1994) 1691 1994年
"Synthesis, Isolation, and Thermolysis of Tetracoordinate 1,2-Oxaphosphetanes Stabilized by Steric Protection"

<Chem. Lett.> (1994) 1487 1994年
"Intramolecular Dehydration of β-Hydroxyalkylphosphonic Acid Monoesters. A Novel Type of Olefin Formation"

<Chem. Lett.> (1994) 1483 1994年
"Reaction of 2,4,6-Tri-┣DBt(/)-┫DB-butylselenobenzaldegyde with Sterically Crowded Diazo Compounds. Formation of Seleniranes"

<Chem. Lett.> (1994) 1289 1994年
"Synthesis, Structure, and Thermolysis of a 1,5-Dioxa-4λ⁵-phosphaspiro〔3.3〕heptane : a Novel Pentacoordinate 1,2-Oxaphosphetane"

<J. Am. Chem. Soc.> (116) 4509 1994年
"Synthesis and Crystal Structure of an Intermediate of the Germanium-Peterson Reaction"

J. Org. Chem. 59(2) 491-493 1994年
Crystal Structure and Reactivity of a Pentacoordinate 1,2-Oxastannetanide : An Intermediate of the Tin-Peterson Reaction

J. Am. Chem. Soc. 115(6) 2507-2508 1993年
Synthesis, Structure, and Thermolysis of a 3-Methoxycarbonyl-1,2λ⁵-oxaphosphetane

Angew. Chem. , Int. Ed. Engl. 32(6) 869-870 1993年
Synthesis of Δ³-1,3,4-Telluradiazolines, a Novel Tellurium-Containing Heterocycle

Chem. Lett. (6) 1047-1048 1993年
1,1,3,3-Tetramethylindantellone, the First Telluroketone Stable in Solution

J. Am. Chem. Soc. 115(15) 7019-7020 1993年
Synthesis of Optically Active Phosphorus Compounds via Metal Phosphinite Generated by Reaction of Optically Active Selenophosphinates with Phenyllithium

Takayuki Kawashima, Hiroki Iwanaga, Renji Okazaki

Chem. Lett. (9) 1531-1532 1993年
Synthesis, Structures, and Thermolyses of Tetracoordinate 1,2-Oxaselenetanes

J. Am. Chem. Soc. 115(22) 10434-10435 1993年
Synthesis and X-ray Crystallographic Analysis of Pentacoordinate 1, 2-Oxasiletanides, Intermediates of the Peterson Reaction

J. Am. Chem. Soc 114(19) 7598-7599 1992年
Tandem Peterson-Michael Reaction Using α-Silylalkylphosphine Chalocogenides and Horner-Emmons Reaction

Phosphorus, Sulfur, and Silicon 69 293 1992年
The Phospha-Cope Rearrangement of 3-Phospha-1,5-hexadiene Dirivatives Bearing a Hydroxyl Group

Takayuki Kawashima, Dae Jong Park, Shinobu Murata, Renji Okazaki, Naoki Inamoto

Chemistry Letters (8) 1607-1610 1992年
Novel Synthetic Route to Isolable Pentacoordinate 1,2-Oxaphosphetanes and Mechanism of Their Thermolysis, the Second Step of the Wittig Reaction

Journal of the American Chemical Society 114(10) 4008-4010 1992年
The 1,3-Diastereoselective Synthesis of 2-Hydroxyalkyl-phosphine Oxides Based on a Chiral Phosphorus Center

Phosphorus, Sulfur, and Silicon 60 21 1991年

書籍等出版物

11

"Modern Carbonyl 01efination"

Wiley-VCH, 2004年
「21世紀の有機ケイ素化学―機能性物質科学の宝庫―」

シーエムシー出版 2004年
「有機金属反応剤ハンドブック」

化学同人 2003年
"Four-membered Rings with 1 Phosphorus Atom" "jointly authored"

Phosphorus-Carbon Heterocyclic Chemistry: The Rise of a New Domain, Pergamon 2001年
"Four-membered Rings with 1 Phosphorus Atom" "jointly authored" Phosphorus-Carbon Heterocyclic Chemistry: The Rise of a New

Domain, Pergamon 2001年

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所属学協会

6

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共同研究・競争的資金等の研究課題

6

斬新な特定位置占拠型配位子の設計と高配位典型元素化合物の創製

科学研究費補助金 2003年 - 2007年
Development of novel ligands occupying the specified position and their application to the synthesis of new hypervalent compounds

Grant-in-Aid for Scientific Research 2003年 - 2007年
ヘテロ原子の特徴を活用した新規反応の開発

科学研究費補助金 1990年
高配位典型元素を有するヘテロ原子化合物の合成と反応

科学研究費補助金 1990年
Development of Novel Reactions Utilizing Characteristics of Heteroatoms

Grant-in-Aid for Scientific Research 1990年

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