研究者業績

川島隆幸

カワシマタカユキ (Takayuki Kawashima)

基本情報

所属: 学習院大学理学部客員教授
東京大学大学院理学系研究科名誉教授

学位: 理学博士(東京大学)
理学修士(東京大学)

J-GLOBAL ID: 200901052041105974
researchmap会員ID: 1000013812

研究キーワード

4

研究分野

3

経歴

21

1993年 - 1998年

東京大学大学院理学系研究科助教授
1993年 - 1998年

Associate Professor, Graduate School of
1998年

- 東京大学大学院理学系研究科教授
1998年

- Professor, Graduate School of Science, The
1996年 - 1997年

京都大学化学研究所客員助教授

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学歴

4

委員歴

5

MISC

156

Preparation of an aliphatic-substituted hypervalent iodine compound, tetracoordinate 1,2-iodoxetane 1-oxide, and its application to oxidation

N Kano, M Ohashi, K Hoshiba, T Kawashima

TETRAHEDRON LETTERS 45(44) 8173-8175 2004年10月
Isolation of a Se-nitrososelenol: A new class of reactive nitrogen species relevant to protein Se-nitrosation

K Shimada, K Goto, T Kawashima, N Takagi, YK Choe, S Nagase

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 126(41) 13238-13239 2004年10月
Evaluation of sigma-donating ability of a 9-phosphatriptycene and its application to catalytic reactions

T Agou, J Kobayashi, T Kawashima

CHEMISTRY LETTERS 33(8) 1028-1029 2004年8月
Reactivity control of an allylsilane bearing a 2-(phenylazo)phenyl group by photoswitching of the coordination number of silicon

N Kano, M Yamamura, T Kawashima

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 126(20) 6250-6251 2004年5月
Synthesis and structure of a novel symmetrically substituted phosphatriptycene oxide

J Kobayashi, T Agou, T Kawashima

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS 179(4-5) 959-960 2004年4月
"Synthesis, Structure, and Thermolysis of Pentacoordinate 1,2-Oxastibetanes"

Phosphorus, Sulfur, Silicon Relat. Elem., 179, 849-852 2004年
Synthesis structure and reactivity of a symmetrically substituted 9-phosphatriptycene oxide and its derivatives

T Agou, J Kobayashi, T Kawashima

HETEROATOM CHEMISTRY 15(6) 437-446 2004年
"Isolation of a Cyclic Intermediate in the Reaction of a Phosphorus Ylide with Elemental Sulfur: Synthesis, Structure, and Reactivity of a 1,2σ5-Thiaphosphirane"

Chem. Lett., 33, 1434-1435 2004年
A novel and convenient synthetic route to a 9-phosphatriptycene and systematic comparisons of 9-phosphatriptycene derivatives

J Kobayashi, T Agou, T Kawashima

CHEMISTRY LETTERS 32(12) 1144-1145 2003年12月
Syntheses and structural characterizations of a novel bowl-type germanol and its derivatives

K Goto, Shimo, I, T Kawashima

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 76(12) 2389-2394 2003年12月
Synthesis, crystal structure, and photoreaction of a disiloxane bearing two 2-(phenylazo)phenyl groups

N Kano, M Yamamura, F Komatsu, T Kawashima

JOURNAL OF ORGANOMETALLIC CHEMISTRY 686(1-2) 192-197 2003年11月
Synthesis, structure, and thermolysis of a pentacoordinate 1,2-oxastibetane

Y Uchiyama, N Kano, T Kawashima

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 125(44) 13346-13347 2003年11月
Four-membered heterocyclic compounds containing high coordinate group 16 elements

T Kawashima

COORDINATION CHEMISTRY REVIEWS 244(1-2) 137-147 2003年9月
Synthesis and crystal structure of a novel heterocyclic compound bearing a pentacoordinate germanium atom and a deprotonated HMPA moiety

N Kano, S Goto, T Kawashima

ORGANOMETALLICS 22(5) 1152-1155 2003年3月
"Isolation and Structural Analysis of Novel Conformational Isomers of the m-Xylylene-bridged Calix[6]arenes: the "Partial Cone" and "Inverted Cone" Isomers"

Tetrahedron Lett., 44, 1171-1174 2003年
"Syntheses, Structures, and Thermolyses of Three- and Four-Membered Heterocyclic Compounds Containing Highly Coordinate Main Group Elements"

Bull. Chem. Soc. Jpn., 76, 471-483 2003年
"Reaction of Stable Sulfenic and Selenenic Acids Containing a Bowl-type Steric Protection Group with a Phosphine: The First Elucidation of the Mechanism of Reduction of Sulfenic and Selenenic Acids"

Chem. Lett., 32, 1080-1081 2003年
A bowl-shaped triarylphosphane with a large cone angle: Synthesis and crystallographic analysis of a [(PdX2)(3)(PR3)(2)]-type complex

Y Ohzu, K Goto, T Kawashima

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 42(46) 5714-5717 2003年
"Synthesis and Structure of the First Pentacoordinate 1,2σ⁵-Selenaphosphirane" "jointly authored"

J. Am. Chem. Soc. 124, 9706-9707 2002年
"Synthesis, Structure, and Thermolysis of a Novel Spirotellurane Bearing Two 1,2-Oxatelluretane Rings, 1,5-Dioxa-4λ⁴-telluraspiro[3.3]heptane: Oxirane and Olefin Formation Reactions" "jointly authored"

Tetrahedron Lett. 43, 6775-6778 2002年
"Hypercoordination to a Saturated Carbon Atom" "jointly authored"

Tetrahedron Lett. 43, 5759-5762 2002年
"Synthesis and Structure of the First Pentacoordinate Thiasiliranides" "jointly authored"

Organomet. Chem. 643-644, 504-507 2002年
"Fluoride Ion Abstraction of Phosphonium Cations from Their Counter Anion: A Novel Synthetic Method of Fluorophosphoranes" "jointly authored"

Chem. Lett. 2002, 268-269 2002年
"Cycloaddition Reactions of an Iminophosphorane Bearing the Martin Ligand with Some Double-Bond Compounds: Syntheses, Structures and Thermolyses of a 1,3,2λ⁵-Oxazaphosphetidine and a 1,3,2λ⁵-Diazaphosphetidine-4-thione" "jointly a・・・

Polyhedron 21, 657-665 2002年

"Cycloaddition Reactions of an Iminophosphorane Bearing the Martin Ligand with Some Double-Bond Compounds: Syntheses, Structures and Thermolyses of a 1,3,2λ<sup>5</sup>-Oxazaphosphetidine and a 1,3,2λ<sup>5</sup>-Diazaphosphetidine-4-thione" "jointly authored"
"Synthesis Structure and Bonding Properties of 5-Carbaphosphatranes: A New Class of Main Group Atrane" "jointly authored"

J. Am. Chem. Soc. 124, 3703-3712 2002年
"Synthesis of Novel Triarylphosphines Bearing a m-Terphenyl-based Dendrimer-type Framework" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem. 177, 2179 2002年
"Novel Synthetic Method of Fluorophosphoranes by Fluoride Ion Abstraction from Tetrafluoroborate" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem. 177, 2041 2002年
"Synthesis of the First Stable Pentacoordinate Selenaphosphirane" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem. 177, 2039-2040 2002年
"Bonding Properties of 5-Carbaphosphatranes" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem. 177, 2037-2038 2002年
"Synthesis of Four-and Five-membered Heterocycles Derived from an Iminophosphorane" "jointly authored"

Phosphorus, Sulfer, Silicon Relat. Elem. 177, 1685-1687 2002年
"Reactions of 1-Hydro-5-Carbaphosphatrance: Tautomerization between Five Coordinate and Three Coordinate Species" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem. 177, 1405-1407 2002年
"Synthesis and Structure of the First Pentacoordinate 1,2σ⁵-Selenaphosphirane" "jointly authored"

J. Am. Chem. Soc. 124, 9706-9707 2002年
"Synthesis, Structure, and Thermolysis of a Novel Spirotellurane Bearing Two 1,2-Oxatelluretane Rings, 1,5-Dioxa-4λ⁴-telluraspiro[3.3]heptane: Oxirane and Olefin Formation Reactions" "jointly authored"

Tetrahedron Lett. 43, 6775-6778 2002年
"Hypercoordination to a Saturated Carbon Atom" "jointly authored"

Tetrahedron Lett. 43, 5759-5762 2002年
"Synthesis and Structure of the First Pentacoordinate Thiasiliranides" "jointly authored"

Organomet. Chem. 643-644, 504-507 2002年
"Fluoride Ion Abstraction of Phosphonium Cations from Their Counter Anion: A Novel Synthetic Method of Fluorophosphoranes" "jointly authored"

Chem. Lett. 2002, 268-269 2002年
"Cycloaddition Reactions of an Iminophosphorane Bearing the Martin Ligand with Some Double-Bond Compounds: Syntheses, Structures and Thermolyses of a 1,3,2λ⁵-Oxazaphosphetidine and a 1,3,2λ5-Diazaphosphetidine-4-thione" "jointly authored"

Polyhedron 21, 657-665 2002年
"Synthesis Structure and Bonding Properties of 5-Carbaphosphatranes: A New Class of Main Group Atrane" "jointly authored"

J. Am. Chem. Soc. 124, 3703-3712 2002年
"Synthesis of Novel Triarylphosphines Bearing a m-Terphenyl-based Dendrimer-type Framework" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem. 177, 2179 2002年
"Novel Synthetic Method of Fluorophosphoranes by Fluoride Ion Abstraction from Tetrafluoroborate" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem. 177, 2041 2002年
"Synthesis of the First Stable Pentacoordinate Selenaphosphirane" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem. 177, 2039-2040 2002年
"Bonding Properties of 5-Carbaphosphatranes" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem. 177, 2037-2038 2002年
"Synthesis of Four-and Five-membered Heterocycles Derived from an Iminophosphorane" "jointly authored"

Phosphorus, Sulfer, Silicon Relat. Elem. 177, 1685-1687 2002年
"Reactions of 1-Hydro-5-Carbaphosphatrance: Tautomerization between Five Coordinate and Three Coordinate Species" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem. 177, 1405-1407 2002年
"Reversible Photo-Control of the Coordination Number of Silicon in a Tetrafluorosilicate Bearing a 2-(Phenylazo)phenyl Group" "jointly authored"

J. Am. Chem. Soc. 123, 10778-10779 2001年
"The First Direct Oxidative Conversion of a Selenol to a Stable Selenenic Acid: Experimental Demonstration of Three Processes Included in the Catalytic Cycle of Glutathione Peroxidase" "jointly authored"

Org. Lett. 3, 3569-3572 2001年
"A Disilane Containing Two Heptacoordinate Silicone Atoms and Dithiocarboxylate Ligands" "jointly authored"

Angew. Chem. Int. Ed. 40, 3450-3452 2001年
"Conformational Mobility of the Calix[6]arenes with Allyl and Ethyl Groups on the Lower Rim" "jointly authored"

Bull. Chem. Soc. Jpn. 74, 2167-2174 2001年
"Structural Characterization of a Pentacoordinate Monohydrosilane with the Apical Si-H bond" "jointly authored"

Chem. Heterocyclic Compounds 2001, 1524-1525 2001年
"The First Isolable Pentacoordinate 1,2λ⁵-Azaphosphetine: Synthesis, X-ray Crystallographic Analysis, and Dynamic Behaviour" "jointly authored"

Chem. Commun. 2001, 2096-2097 2001年

書籍等出版物

11

"Modern Carbonyl 01efination"

Wiley-VCH, 2004年
「21世紀の有機ケイ素化学―機能性物質科学の宝庫―」

シーエムシー出版 2004年
「有機金属反応剤ハンドブック」

化学同人 2003年
"Four-membered Rings with 1 Phosphorus Atom" "jointly authored"

Phosphorus-Carbon Heterocyclic Chemistry: The Rise of a New Domain, Pergamon 2001年
"Four-membered Rings with 1 Phosphorus Atom" "jointly authored" Phosphorus-Carbon Heterocyclic Chemistry: The Rise of a New

Domain, Pergamon 2001年

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所属学協会

6

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共同研究・競争的資金等の研究課題

6

斬新な特定位置占拠型配位子の設計と高配位典型元素化合物の創製

科学研究費補助金 2003年 - 2007年
Development of novel ligands occupying the specified position and their application to the synthesis of new hypervalent compounds

Grant-in-Aid for Scientific Research 2003年 - 2007年
ヘテロ原子の特徴を活用した新規反応の開発

科学研究費補助金 1990年
高配位典型元素を有するヘテロ原子化合物の合成と反応

科学研究費補助金 1990年
Development of Novel Reactions Utilizing Characteristics of Heteroatoms

Grant-in-Aid for Scientific Research 1990年

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