Curriculum Vitaes

Takayuki Kawashima

(川島隆幸)

Profile Information

Affiliation: Visiting Professor, Faculty of Science, Gakushuin University
Professor Emeritus, Graduate School of Science, The University of Tokyo

Degree: (BLANK)(The University of Tokyo)
(BLANK)(The University of Tokyo)

J-GLOBAL ID: 200901052041105974
researchmap Member ID: 1000013812

Research Interests

4

Research Areas

3

Research History

21

1993 - 1998

Graduate School of Science, The University of Tokyo
1993 - 1998

Associate Professor, Graduate School of
1998

- 東京大学大学院理学系研究科教授
1998

- Professor, Graduate School of Science, The
1996 - 1997

Institute for Chemical Research, Kyoto University

Education

4

- 1974

The University of Tokyo
- 1974

Chemistry, Graduate School of Science, The University of Tokyo
- 1969

Faculty of Science, The University of Tokyo
- 1969

Chemistry, Faculty of Science, The University of Tokyo

Committee Memberships

5

Misc.

156

Preparation of an aliphatic-substituted hypervalent iodine compound, tetracoordinate 1,2-iodoxetane 1-oxide, and its application to oxidation

N Kano, M Ohashi, K Hoshiba, T Kawashima

TETRAHEDRON LETTERS, 45(44) 8173-8175, Oct, 2004
Isolation of a Se-nitrososelenol: A new class of reactive nitrogen species relevant to protein Se-nitrosation

K Shimada, K Goto, T Kawashima, N Takagi, YK Choe, S Nagase

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 126(41) 13238-13239, Oct, 2004
Evaluation of sigma-donating ability of a 9-phosphatriptycene and its application to catalytic reactions

T Agou, J Kobayashi, T Kawashima

CHEMISTRY LETTERS, 33(8) 1028-1029, Aug, 2004
Reactivity control of an allylsilane bearing a 2-(phenylazo)phenyl group by photoswitching of the coordination number of silicon

N Kano, M Yamamura, T Kawashima

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 126(20) 6250-6251, May, 2004
Synthesis and structure of a novel symmetrically substituted phosphatriptycene oxide

J Kobayashi, T Agou, T Kawashima

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 179(4-5) 959-960, Apr, 2004
"Synthesis, Structure, and Thermolysis of Pentacoordinate 1,2-Oxastibetanes"

Phosphorus, Sulfur, Silicon Relat. Elem.,, 179, 849-852, 2004
Synthesis structure and reactivity of a symmetrically substituted 9-phosphatriptycene oxide and its derivatives

T Agou, J Kobayashi, T Kawashima

HETEROATOM CHEMISTRY, 15(6) 437-446, 2004
"Isolation of a Cyclic Intermediate in the Reaction of a Phosphorus Ylide with Elemental Sulfur: Synthesis, Structure, and Reactivity of a 1,2σ5-Thiaphosphirane"

Chem. Lett.,, 33, 1434-1435, 2004
A novel and convenient synthetic route to a 9-phosphatriptycene and systematic comparisons of 9-phosphatriptycene derivatives

J Kobayashi, T Agou, T Kawashima

CHEMISTRY LETTERS, 32(12) 1144-1145, Dec, 2003
Syntheses and structural characterizations of a novel bowl-type germanol and its derivatives

K Goto, Shimo, I, T Kawashima

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 76(12) 2389-2394, Dec, 2003
Synthesis, crystal structure, and photoreaction of a disiloxane bearing two 2-(phenylazo)phenyl groups

N Kano, M Yamamura, F Komatsu, T Kawashima

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 686(1-2) 192-197, Nov, 2003
Synthesis, structure, and thermolysis of a pentacoordinate 1,2-oxastibetane

Y Uchiyama, N Kano, T Kawashima

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(44) 13346-13347, Nov, 2003
Four-membered heterocyclic compounds containing high coordinate group 16 elements

T Kawashima

COORDINATION CHEMISTRY REVIEWS, 244(1-2) 137-147, Sep, 2003
Synthesis and crystal structure of a novel heterocyclic compound bearing a pentacoordinate germanium atom and a deprotonated HMPA moiety

N Kano, S Goto, T Kawashima

ORGANOMETALLICS, 22(5) 1152-1155, Mar, 2003
"Isolation and Structural Analysis of Novel Conformational Isomers of the m-Xylylene-bridged Calix[6]arenes: the "Partial Cone" and "Inverted Cone" Isomers"

Tetrahedron Lett.,, 44, 1171-1174, 2003
"Syntheses, Structures, and Thermolyses of Three- and Four-Membered Heterocyclic Compounds Containing Highly Coordinate Main Group Elements"

Bull. Chem. Soc. Jpn.,, 76, 471-483, 2003
"Reaction of Stable Sulfenic and Selenenic Acids Containing a Bowl-type Steric Protection Group with a Phosphine: The First Elucidation of the Mechanism of Reduction of Sulfenic and Selenenic Acids"

Chem. Lett.,, 32, 1080-1081, 2003
A bowl-shaped triarylphosphane with a large cone angle: Synthesis and crystallographic analysis of a [(PdX2)(3)(PR3)(2)]-type complex

Y Ohzu, K Goto, T Kawashima

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 42(46) 5714-5717, 2003
"Synthesis and Structure of the First Pentacoordinate 1,2σ⁵-Selenaphosphirane" "jointly authored"

J. Am. Chem. Soc., 124, 9706-9707, 2002
"Synthesis, Structure, and Thermolysis of a Novel Spirotellurane Bearing Two 1,2-Oxatelluretane Rings, 1,5-Dioxa-4λ⁴-telluraspiro[3.3]heptane: Oxirane and Olefin Formation Reactions" "jointly authored"

Tetrahedron Lett., 43, 6775-6778, 2002
"Hypercoordination to a Saturated Carbon Atom" "jointly authored"

Tetrahedron Lett., 43, 5759-5762, 2002
"Synthesis and Structure of the First Pentacoordinate Thiasiliranides" "jointly authored"

Organomet. Chem., 643-644, 504-507, 2002
"Fluoride Ion Abstraction of Phosphonium Cations from Their Counter Anion: A Novel Synthetic Method of Fluorophosphoranes" "jointly authored"

Chem. Lett., 2002, 268-269, 2002
"Cycloaddition Reactions of an Iminophosphorane Bearing the Martin Ligand with Some Double-Bond Compounds: Syntheses, Structures and Thermolyses of a 1,3,2λ⁵-Oxazaphosphetidine and a 1,3,2λ⁵-Diazaphosphetidine-4-thione" "jointly a・・・

Polyhedron, 21, 657-665, 2002

"Cycloaddition Reactions of an Iminophosphorane Bearing the Martin Ligand with Some Double-Bond Compounds: Syntheses, Structures and Thermolyses of a 1,3,2λ<sup>5</sup>-Oxazaphosphetidine and a 1,3,2λ<sup>5</sup>-Diazaphosphetidine-4-thione" "jointly authored"
"Synthesis Structure and Bonding Properties of 5-Carbaphosphatranes: A New Class of Main Group Atrane" "jointly authored"

J. Am. Chem. Soc., 124, 3703-3712, 2002
"Synthesis of Novel Triarylphosphines Bearing a m-Terphenyl-based Dendrimer-type Framework" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem., 177, 2179, 2002
"Novel Synthetic Method of Fluorophosphoranes by Fluoride Ion Abstraction from Tetrafluoroborate" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem., 177, 2041, 2002
"Synthesis of the First Stable Pentacoordinate Selenaphosphirane" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem., 177, 2039-2040, 2002
"Bonding Properties of 5-Carbaphosphatranes" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem., 177, 2037-2038, 2002
"Synthesis of Four-and Five-membered Heterocycles Derived from an Iminophosphorane" "jointly authored"

Phosphorus, Sulfer, Silicon Relat. Elem., 177, 1685-1687, 2002
"Reactions of 1-Hydro-5-Carbaphosphatrance: Tautomerization between Five Coordinate and Three Coordinate Species" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem., 177, 1405-1407, 2002
"Synthesis and Structure of the First Pentacoordinate 1,2σ⁵-Selenaphosphirane" "jointly authored"

J. Am. Chem. Soc., 124, 9706-9707, 2002
"Synthesis, Structure, and Thermolysis of a Novel Spirotellurane Bearing Two 1,2-Oxatelluretane Rings, 1,5-Dioxa-4λ⁴-telluraspiro[3.3]heptane: Oxirane and Olefin Formation Reactions" "jointly authored"

Tetrahedron Lett., 43, 6775-6778, 2002
"Hypercoordination to a Saturated Carbon Atom" "jointly authored"

Tetrahedron Lett., 43, 5759-5762, 2002
"Synthesis and Structure of the First Pentacoordinate Thiasiliranides" "jointly authored"

Organomet. Chem., 643-644, 504-507, 2002
"Fluoride Ion Abstraction of Phosphonium Cations from Their Counter Anion: A Novel Synthetic Method of Fluorophosphoranes" "jointly authored"

Chem. Lett., 2002, 268-269, 2002
"Cycloaddition Reactions of an Iminophosphorane Bearing the Martin Ligand with Some Double-Bond Compounds: Syntheses, Structures and Thermolyses of a 1,3,2λ⁵-Oxazaphosphetidine and a 1,3,2λ5-Diazaphosphetidine-4-thione" "jointly authored"

Polyhedron, 21, 657-665, 2002
"Synthesis Structure and Bonding Properties of 5-Carbaphosphatranes: A New Class of Main Group Atrane" "jointly authored"

J. Am. Chem. Soc., 124, 3703-3712, 2002
"Synthesis of Novel Triarylphosphines Bearing a m-Terphenyl-based Dendrimer-type Framework" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem., 177, 2179, 2002
"Novel Synthetic Method of Fluorophosphoranes by Fluoride Ion Abstraction from Tetrafluoroborate" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem., 177, 2041, 2002
"Synthesis of the First Stable Pentacoordinate Selenaphosphirane" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem., 177, 2039-2040, 2002
"Bonding Properties of 5-Carbaphosphatranes" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem., 177, 2037-2038, 2002
"Synthesis of Four-and Five-membered Heterocycles Derived from an Iminophosphorane" "jointly authored"

Phosphorus, Sulfer, Silicon Relat. Elem., 177, 1685-1687, 2002
"Reactions of 1-Hydro-5-Carbaphosphatrance: Tautomerization between Five Coordinate and Three Coordinate Species" "jointly authored"

Phosphorus, Sulfur, Silicon Relat. Elem., 177, 1405-1407, 2002
"Reversible Photo-Control of the Coordination Number of Silicon in a Tetrafluorosilicate Bearing a 2-(Phenylazo)phenyl Group" "jointly authored"

J. Am. Chem. Soc., 123, 10778-10779, 2001
"The First Direct Oxidative Conversion of a Selenol to a Stable Selenenic Acid: Experimental Demonstration of Three Processes Included in the Catalytic Cycle of Glutathione Peroxidase" "jointly authored"

Org. Lett., 3, 3569-3572, 2001
"A Disilane Containing Two Heptacoordinate Silicone Atoms and Dithiocarboxylate Ligands" "jointly authored"

Angew. Chem. Int. Ed., 40, 3450-3452, 2001
"Conformational Mobility of the Calix[6]arenes with Allyl and Ethyl Groups on the Lower Rim" "jointly authored"

Bull. Chem. Soc. Jpn., 74, 2167-2174, 2001
"Structural Characterization of a Pentacoordinate Monohydrosilane with the Apical Si-H bond" "jointly authored"

Chem. Heterocyclic Compounds, 2001, 1524-1525, 2001
"The First Isolable Pentacoordinate 1,2λ⁵-Azaphosphetine: Synthesis, X-ray Crystallographic Analysis, and Dynamic Behaviour" "jointly authored"

Chem. Commun., 2001, 2096-2097, 2001

Books and Other Publications

11

"Modern Carbonyl 01efination"

Wiley-VCH,, 2004
「21世紀の有機ケイ素化学―機能性物質科学の宝庫―」

シーエムシー出版, 2004
「有機金属反応剤ハンドブック」

化学同人, 2003
"Four-membered Rings with 1 Phosphorus Atom" "jointly authored"

Phosphorus-Carbon Heterocyclic Chemistry: The Rise of a New Domain, Pergamon, 2001
"Four-membered Rings with 1 Phosphorus Atom" "jointly authored" Phosphorus-Carbon Heterocyclic Chemistry: The Rise of a New

Domain, Pergamon, 2001

Professional Memberships

6

Research Projects

6

斬新な特定位置占拠型配位子の設計と高配位典型元素化合物の創製

科学研究費補助金, 2003 - 2007
Development of novel ligands occupying the specified position and their application to the synthesis of new hypervalent compounds

Grant-in-Aid for Scientific Research, 2003 - 2007
ヘテロ原子の特徴を活用した新規反応の開発

科学研究費補助金, 1990
高配位典型元素を有するヘテロ原子化合物の合成と反応

科学研究費補助金, 1990
Development of Novel Reactions Utilizing Characteristics of Heteroatoms

Grant-in-Aid for Scientific Research, 1990

To the list screen

MENU