The SiSi bond of a pentacoordinated disilicate was readily cleaved by treatment with 2,3-dichloro-5,6-dicyano-p-benzoquinone in the presence of sodium carbonate under mild conditions. The bond cleavage did not proceed under the same conditions aft...
The first dianionic compounds bearing a bond between two pentacoordinated germanium atoms have been synthesized in a stable form as candidates for a core unit to construct unprecedented structures in group 14 element chemistry. X-ray crystallograp...
The title trans and cis isomers (trans-3 and cis-3) were successfully synthesized as stable compounds by taking advantage of the Martin ligand. The X-ray crystallographic analysis of trans-3 showed that it has a distorted pseudotrigonal bipyramida...
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 87(9) 1005-1012 2014年9月 [査読有り]
Tetracoordinated and pentacoordinated 1,2-thiazetidines bearing the Martin ligand, trans-5 and trans-6, were synthesized as stable compounds. The X-ray crystallographic analyses showed that trans-5 and trans-6 have distorted pseudotrigonal bipyram...