We report conjugated methine compounds generated from N-arylpyridiniums and amines; streptocyanines can be used as a new activation mode for amine catalysis and applied to the conversion of pyridine rings to benzene rings.
Ligand coupling on sulfur, as an alternative to transition-metal-catalyzed cross-coupling reactions, is a useful method for connecting sp2 carbons. Although pioneered more than 50 years ago, its synthetic utility has been overlooked unti...
Organic & Biomolecular Chemistry 20(48) 9600-9603 2022 [Refereed]
Trifluoromethylated thermally activated delayed fluorescent molecule 4[Cz(CF3)2]IPN has been demonstrated as a versatile photocatalyst that facilitates radical reactions via electron transfer and dearomative cycloaddition via...
Abstracts of Symposium on Physical Organic Chemistry 2009(0) 28-28 2009
The polarity of a chemical bond is an important factor that affects its reactivity. We report here a method for reversing polarity of a hydrogen atom of water, which meant conversion of a proton (H+) to a hydride (H–), by using a hexacoordinated p...